Mass Transfer
For a binary mixture with low relative volatility,

An azeotrope may be formed during distillation
Use high pressure distillation
Use steam distillation
Use molecular distillation

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Mass Transfer
Solvent extraction is the terminology applied to the liquid-liquid extraction, which is preferred for the separation of the components of liquids, when

Extracting solvent is cheaply & abundantly available
One of the liquid components is heat sensitive
One of the liquid components has very high affinity towards the solvent
Viscosity of liquid components is very high

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