Mass Transfer
For a binary mixture with low relative volatility,

Use high pressure distillation
Use molecular distillation
An azeotrope may be formed during distillation
Use steam distillation

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Mass Transfer
Steam distillation is used to

Increase the total pressure of distillation
Avoid thermal decomposition of a component
Reduce the number of plates
Increase the efficiency of separation

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Mass Transfer
In an operating distillation column, the

Driving force for the liquid flow is its specific weight
Vapors and liquids are at their dew point and bubble point respectively
Highest temperature is encountered at the top of the column
Driving force for the vapor flow is the pressure drop, as the pressure decreases gradually from the bottom to the top of the column

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