Mass Transfer
For a binary mixture with low relative volatility,

An azeotrope may be formed during distillation
Use high pressure distillation
Use molecular distillation
Use steam distillation

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Mass Transfer
Solvent extraction is the terminology applied to the liquid-liquid extraction, which is preferred for the separation of the components of liquids, when

One of the liquid components is heat sensitive
Viscosity of liquid components is very high
Extracting solvent is cheaply & abundantly available
One of the liquid components has very high affinity towards the solvent

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