Chemical Engineering Thermodynamics
Choose the condition that must be specified in order to liquify CO₂ (triple point for CO₂ is - 57°C and 5.2 atm).

Pressure must be kept below 5.2 atm
Temperature must be kept above - 57°C
Pressure must be kept below 5.2 atm. and temperature must be kept above 57°C
Pressure and temperature must be kept below 5.2 atm. and - 57°C respectively

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Chemical Engineering Thermodynamics
The third law of thermodynamics states that the

Gases having same reduced properties behave similarly
None of these
Heat capacity of a crystalline solid is zero at absolute zero temperature
Heat transfer from low temperature to high temperature source is not possible without external work

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Chemical Engineering Thermodynamics
On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)S and the slope of the reversible isothermal line (∂P/∂V)T are related as (where, y = Cp/Cv) )

(∂P/∂V)S = [(∂P/∂V)T]Y
(∂P/∂V)S = y(∂P/∂V)T
(∂P/∂V)S = 1/y(∂P/∂V)T
(∂P/∂V)S = (∂P/∂V)T

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