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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For a reversible process involving only pressure-volume work

(dF)T, p > 0
(dF)T, p = 0
(dF)T, p < 0
(dA)T, v < 0

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Chemical Engineering Thermodynamics
For a cyclic process, a fixed ratio between heat and work

May exist
Is difficult to predict
Always exists
Never exists

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Chemical Engineering Thermodynamics
Cp of a gas at its critical temperature and pressure

Becomes zero
Becomes infinity
Equals 0.24 kcal/kmol °K
Equals 1 kcal/kmol °K

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Chemical Engineering Thermodynamics
Fugacity and pressure are numerically not equal for the gases

Both A and B
In ideal state
At standard state
At low temperature and high pressure

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Chemical Engineering Thermodynamics
If atmospheric temperature and dew point are nearly equal, then the relative humidity is

Almost 100%
Unpredictable
Zero
50%

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DQ = CvdT + PdV
DQ = CpdT + Vdp
DE = Tds - PdV

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