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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The energy of activation of exothermic reaction is

Not possible to predict
Zero
Negative
Very large compared to that for en-dothermic reaction

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Chemical Engineering Thermodynamics
The free energy change for a chemical reaction is given by (where, K = equilibrium constant)

RT lnK
-RT lnK
T lnK
-R lnK

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Chemical Engineering Thermodynamics
When pressure is applied on the system, ice ⟷ water, then

Evaporation of water will take place
More water will be formed
Equilibrium can not be established
More ice will be formed

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Chemical Engineering Thermodynamics
A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system

Its internal energy (U) decreases and its entropy (S) increases
U decreases but S is constant
U and S both decreases
U is constant but S decreases

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Chemical Engineering Thermodynamics
The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of

T and Z
T
T and P
T, P and Z

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Chemical Engineering Thermodynamics
Equilibrium constant decreases as the temperature

Decreases, for an exothermic reaction
Increases, for an endothermic reaction
None of these
Increases, for an exothermic reaction

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