Mass Transfer
Can the efficiency of a plate in the distillation tower be greater than 100%?

Never
Yes
Yes ; if the reflux ratio is maximum
Normally not; but is possible if infinite number of plates are put

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Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Total pressure is less
Saturated steam is used for steam distillation
Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Temperature is less

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