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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
With increase in pressure (above atmospheric pressure), the Cp of a gas

Increases
First decreases and then increases
Remains unchanged
Decreases

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Chemical Engineering Thermodynamics
Any substance above its critical temperature exists as

Gas
Liquid
Solid
Saturated vapour

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Same in both the phases
More in vapour phase
Replaced by chemical potential which is more in vapour phase
More in liquid phase

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Chemical Engineering Thermodynamics
Activity co-efficient is a measure of the

None of these
Vapour pressure of liquid
Departure from ideal solution behaviour
Departure of gas phase from idea] gas law

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Chemical Engineering Thermodynamics
Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants)

(atm)Δx, when Δx is negative
Dimensionless, when Δx = 0
(atm)Δx, when Δx is positive
(atm)Δx2, when Δx > 0

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Chemical Engineering Thermodynamics
The entropy change in a reversible isothermal process, when an ideal gas expands to four times its initial volume is

R loge 4
Cv log10 4
R log10 4
Cv loge 4

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