Chemical Engineering Thermodynamics
Free energy

Remains unchanged in reversible processes carried at constant temperature and pressure
All of these
Change during a spontaneous process has a negative value
Decreases in all spontaneous (or irreversible) processes

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Chemical Engineering Thermodynamics
High pressure steam is expanded adiabati-cally and reversibly through a well insulated turbine, which produces some shaft work. If the enthalpy change and entropy change across the turbine are represented by ΔH and ΔS respectively for this process:

Δ H ≠ 0 and ΔS ≠ 0
Δ H = 0 and ΔS = 0
Δ H ≠ 0 and ΔS = 0
Δ H = 0 and ΔS ≠ 0

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Chemical Engineering Thermodynamics
The necessary and sufficient condition for equilibrium between two phases is

The chemical potential of each component should be same in the two phases
The concentration of each component should be same in the two phases
The temperature of each phase should be same
The pressure should be same in the two phases

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