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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The first law of thermodynamics is a restatement of the law of conservation of

Momentum
Mass
Energy
None of these

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Chemical Engineering Thermodynamics
In a reversible process

DW - dE = Tds
Tds - dW + dE >0
DE - dW = Tds
Tds = dE + dW

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Chemical Engineering Thermodynamics
Degree of freedom of a system consisting of a gaseous mixture of H₂ and NH₃ will be

0
2
3
1

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Chemical Engineering Thermodynamics
In case of the decomposition of hydroiodic acid (2HI ⇋ H₂ + I₂), addition of H₂ (at equilibrium condition) will

Increase the partial pressure of I₂
Decrease the partial pressure of HI
Diminish the degree of dissociation of HI
None of these

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Chemical Engineering Thermodynamics
Trouton's ratio is given by (where λb, = molal heat of vaporisation of a substance at its normal boiling point, kcal/kmol Tb = normal boiling point, °K )

λb/Tb
√(Tb/λb)
Tb/λb
√(λb/Tb)

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Chemical Engineering Thermodynamics
In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

More
Unpredictable; depends on the particular reaction
Same
Less

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