Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Only vapor phase follows Raoult's law
Only liquid phase obeys Dalton's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

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Mass Transfer
When acetone is added in a two layer mixture of methyl isobutyl ketone and water at 30°C, the acetone distributes between the two layers and the composition of the layer follows two solubility curves. For this system,

Both the phases become identical at a particular common point on both the solubility curves called the plait point
The distribution curve which is a plot between x (acetone concentration in one phase) and y (acetone concentration in other phase) is analogous to x-y curve used in distillation and absorption termina
All of these
As the acetone concentration increases, the solubility curves approach each other

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