Mass Transfer
In steam distillation, the

Product must be immiscible with water
Temperature is more than 100° C
Temperature is higher than the boiling point of either component
Temperature is 100°C

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Mass Transfer
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of

Vapour pressure of component A to the partial pressure of A
Partial pressure of component A to the total pressure
Vapour pressure of component A to that of component B
Vapour pressure of component A to the total pressure

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