Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

Ax₂
A . x₂²
Ax₁²
Ax₁

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Chemical Engineering Thermodynamics
In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants )

Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero)
Addition of inert gas favours the forward reaction, when Δx is positive
All of these
Pressure has no effect on equilibrium, when Δn = 0

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