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Structure and Properties of Peptides

Structure and Properties of Peptides
The heme is held in place by a bond between

the Fe3+ and cysteine
the Fe3+ and histidine
the Fe2+ and cysteine
the Fe2+ and histidine

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Structure and Properties of Peptides
The resonance structures that can be drawn for the peptide bond indicate that the peptide bond

is still not completely understood
has partial double bond character
both (a) and (b)
is stronger than an ordinary single bond

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Structure and Properties of Peptides
Peptides in the fully extended chain conformation

are equivalent to the (3-sheet structure
do not occur in nature
also have a cis geometry in their peptide bonds
have Y = F = 180°

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Structure and Properties of Peptides
What was the first protein whose complete tertiary structure was determined?

Myoglobin
Pancreatic ribonuclease
Pancreatic DNase
Lysozyme

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Structure and Properties of Peptides
When pO2 = Kd of myoglobin, the fractional saturation (YO2) is about

1.7
0.5
0.9
0.1

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Structure and Properties of Peptides
The different orders of protein structure are determined by all of the following bond types except

phospho-diester bonds
hydrogen bonds
disulfide bridges
peptide bonds

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