Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water Xw in the vapour phase satisfies

0 < Xw < 0.5
Xw = 0.5
0.5 < Xw < 1.0
Xw = 1.0

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Stoichiometry
Pure aniline is evaporating through a stagnant air film of 1 mm thickness at 300 K and a total pressure of 100 KPa. The vapor pressure of aniline at 300 K is 0.1 KPa. The total molar concentration under these conditions is 40.1 mole/m³ . The diffusivity of aniline in air is 0.74xl0⁻⁵m²/s.The numerical value of mass transfer co-efficient is 7.4 x 10⁻³. The rate of evaporation of aniline is 2.97 x 10⁻⁴. Its units are

Mole/cm². s
Mole/m² . s
Mole/s
Kmole/m² . s

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