Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water Xw in the vapour phase satisfies

Xw = 0.5
Xw = 1.0
0.5 < Xw < 1.0
0 < Xw < 0.5

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Stoichiometry
Heat of reaction is not influenced by

The physical state (e.g., solid, liquid or gaseous) of reactants and products
Whether the reaction is carried out at constant temperature or constant pressure
None of these
The route/method through which final products are obtained

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Stoichiometry
The net heat evolved or absorbed in a chemical process, i.e. total change in the enthalpy of the system is independent of the

Temperature & pressure
State of aggregation & the state of combination at the beginning & the end of the reaction
None of these
Number of intermediate chemical reactions involved

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