Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only liquid phase obeys Dalton's law
Only vapor phase follows Raoult's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

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Mass Transfer
Blowdown in a cooling tower

Increases the scale forming tendencies of water
All of these
Is undesirable
Means discarding a small fraction of circulating water to prevent and limit the concentration of salt and impurities

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