Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Only vapor phase follows Raoult's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only liquid phase obeys Dalton's law

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Mass Transfer
A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state,

Composition of vapors and that of liquid do not vary throughout the column
Reboiler load and condenser load are minimum
The top and bottom compositions correspond to the maximum enrichment available
The top and bottom compositions are unchanged with and without total reflux

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