Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Only vapor phase follows Raoult's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only liquid phase obeys Dalton's law

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Mass Transfer
In an operating distillation column, the

Driving force for the vapor flow is the pressure drop, as the pressure decreases gradually from the bottom to the top of the column
Driving force for the liquid flow is its specific weight
Vapors and liquids are at their dew point and bubble point respectively
Highest temperature is encountered at the top of the column

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