Mass Transfer
Molecular diffusion is caused by the

Potential energy of the molecules
Thermal energy of the molecules
Transfer of molecules from low concentration to high concentration region
Activation energy of the molecules

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Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Temperature is less
Total pressure is less
Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Saturated steam is used for steam distillation

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