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Mass Transfer

Mass Transfer
Mass transfer co-efficient (K) and diffusivity (D) are related according to film theory as

K ∝ D2
K ∝ D1.5
K ∝ D
K ∝ √D

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Mass Transfer
Molecular diffusivity of a liquid

Decreases with temperature
Increases with temperature
Is independent of temperature
May increase or decrease with temperature

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Mass Transfer
Large scale usage of flash distillation is practised in

Polymerisation industry
Soap manufacturing
Petroleum refinning
Ammonia synthesis plant

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Mass Transfer
Tower diameter may be decreased by

Using higher reflux ratio
Use of increased tray spacing
Increasing the vapour flow rate
Increasing the liquid flow rate

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Mass Transfer
An alkaline solution is used to reduce the concentration of carbon dioxide in a stream from 10% to 0.1% by absorption with irreversible chemical reaction. The overall number of transfer units based on gas phase is

100
4.605
0.001
9.21

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Mass Transfer
In continuous distillation, the internal reflux ratio (Ri) and the external reflux ratio (Re) are related as

Ri = Re/(1 - Re)
Ri = Re/(1 + Re)
Ri = (1 - Re)/Re
Ri = Re

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