Heat Transfer
In case of a supercooled solution, which is on the verge of crystallisation, the free energy of the solution as compared to that of the solid is

More or less; depends on the nature of solution
Same
Less
More

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Heat Transfer
Water always boils when its

Saturated vapour pressure equals the external pressure on its surface
Temperature reaches 100° C
Vapour pressure equals 76 cm of Hg
Saturated vapour pressure is less than the atmospheric pressure

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