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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Fugacity co-efficient of a substance is the ratio of its fugacity to

Mole fraction
Pressure
Activity co-efficient
Activity

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
Free energy change at equilibrium is

Zero
Indeterminate
Positive
Negative

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Chemical Engineering Thermodynamics
Degress of freedom at triple point will be

1
3
Zero
2

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Chemical Engineering Thermodynamics
Activity co-efficient is a measure of the

Departure of gas phase from idea] gas law
Vapour pressure of liquid
Departure from ideal solution behaviour
None of these

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Chemical Engineering Thermodynamics
In the equation, PVn = Constant, if the value of n = 0, then it represents a reversible __________ process.

Isobaric
Isothermal
Isentropic
Isometric

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