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Chemical Reaction Engineering

Chemical Reaction Engineering
From collison theory, the reaction rate constant is proportional to

Exp(- E/RT)
Exp(- E/2RT)
Tm.exp(- E/RT)
√T

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Chemical Reaction Engineering
If the time required to complete a definite fraction of reaction varies inversely as the concentration of the reactants, then the order of reaction is

2
1
3

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Chemical Reaction Engineering
In the hydrodealkylation of toluene to benzene, the following reactions occur:C₇H₈ + H₂ → C₆H₆ + CH₄2C₆H₆ ⇋ C₁₂H₁₀ + H₂Toluene and hydrogen are fed to a reactor in a molar ratio 1:5.80% of the toluene gets converted and the selectivity of benzene(defined as moles of benzene formed/moles of toluene converted) is 90%. The fractional conversion of hydrogen is

0.152
0.136
0.144
0.16

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Chemical Reaction Engineering
A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = k + kg
keff = (k+ kg)/2
keff = (kkg)1/2
1/keff = 1/k + 1/kg

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Chemical Reaction Engineering
A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is

0.5
0.33
1
Data insufficient, can't be predicted

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Chemical Reaction Engineering
For the reversible reaction A ⇋ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium?

0.253
0.637
0.338
0.152

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