Chemical Reaction Engineering
A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = k + kg
keff = (k+ kg)/2
keff = (kkg)1/2
1/keff = 1/k + 1/kg

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Chemical Reaction Engineering
For the same residence time, which one will give the maximum conversion?

Stirred tank followed by tubular flow reactor (each of 2.5 litres)
Single stirred tank (v = 5 litres)
Single tubular flow reactor (v = 5 litres)
Two stirred tank (each of 2.5 litres) in series

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Chemical Reaction Engineering
In a zero order reaction, reactants concentration does not change with time and the

Reaction rate is trebled when the initial concentration is trebled
Time for half change is independent of the initial concentration
Time for completion of the reaction is independent of the initial concentration
Time for half change is half the time taken for completion of the reaction

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