Chemical Reaction Engineering
A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = (kkg)1/2
1/keff = 1/k + 1/kg
keff = (k+ kg)/2
keff = k + kg

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Chemical Reaction Engineering
The experimentally determined overall order of the reaction, A + B → C + D, is two. Then the

Reaction is elementary but the molecularity may not be 2
Molecularity of the reaction is 2, but the reaction may not be elementary
Reaction is elementary with a molecularity of 2
Reaction may be elementary with molecularity of 2

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