Mass Transfer
Flash distillation is suitable for separating the constituents of a binary system, which

Form constant boiling azeotrope
Have very close boiling points
Have very wide boiling points
Form minimum boiling azeotrope

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Mass Transfer
Steam distillation is used to

Increase the total pressure of distillation
Avoid thermal decomposition of a component
Reduce the number of plates
Increase the efficiency of separation

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