Heat Transfer
Extremely large or small volumes of fluids are generally best routed through the shell side of a shell and tube heat exchanger, because of the

Low pressure drop
Less corrosion problems
High heat transfer co-efficient
Flexibility possible in the baffle arrangement

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Heat Transfer
In sub-cooled boiling,

Bubbles from heating surface are absorbed by the mass of the liquid
Very large vapour space is necessary
Temperature of the heating surface is more than the boiling point of the liquid
Temperature of the heating surface is less than the boiling point of the liquid

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