Chemical Engineering Thermodynamics
In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants )

Pressure has no effect on equilibrium, when Δn = 0
All of these
Addition of inert gas favours the forward reaction, when Δx is positive
Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero)

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature only
Temperature and pressure only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature, pressure and liquid composition xi only

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