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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Efficiency of a Carnot engine working between temperatures T₁ and T₂ (T₁ < T₂) is

(T₂ - T₁)/T₂
(T₂ - T₁)/T₁
(T₁ - T₂)/T₁
(T₁ - T₂)/T₂

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Chemical Engineering Thermodynamics
Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature.

Zero
Infinity
None of these
Minus infinity

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Chemical Engineering Thermodynamics
At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is

4.238
1.9398
1.572
3.389

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Chemical Engineering Thermodynamics
As the temperature is lowered towards the absolute zero, the value of ∂(ΔF)/∂T, then approaches

Unity
Zero
That of the heat of reaction
Infinity

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Chemical Engineering Thermodynamics
Free energy change at equilibrium is

Negative
Zero
Positive
Indeterminate

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Chemical Engineering Thermodynamics
Fugacity is most helpful in

The study of chemical equilibria involving gases at atmospheric pressure
None of these
Representing actual behaviour of ideal gases
Representing actual behaviour of real gases

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