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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Domestic refrigerator usually works on the __________ refrigeration cycle.

Vapour-ejection
Air
Absorption
Carnot

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Chemical Engineering Thermodynamics
The amount of heat required to decompose a compound into its elements is __________ the heat of formation of that compound from its elements.

More than
Same as
Less than
Not related to

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Chemical Engineering Thermodynamics
In a reversible process

Tds - dW + dE >0
DW - dE = Tds
DE - dW = Tds
Tds = dE + dW

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Chemical Engineering Thermodynamics
Joule-Thomson co-efficient for a perfect gas is

Zero
Positive
Negative
None of these

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Chemical Engineering Thermodynamics
The equation Tds = dE - PdV applies to

Both B and C
Open as well as closed systems
Single phase fluid of varying composition
Single phase fluid of constant composition

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂P)T = -(∂V/∂T)P
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V

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