Mass Transfer
Steam distillation is used to

Reduce the number of plates
Avoid thermal decomposition of a component
Increase the total pressure of distillation
Increase the efficiency of separation

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Mass Transfer
Entrainer used in azeotropic distillation should

Form a new azeotrope of low relative volatility with one of the constituents of the mixture
Form a low boiling azeotrope with one of the constituents of the mixture
Have high viscosity to provide high tray efficiency
Have high latent heat of vaporisation

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