Mass Transfer
Azeotropic distillation is employed to separate

High boiling mixture
Constant boiling mixture
Heat sensitive materials
Mixture with very high relative volatility

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Mass Transfer
Fenske's equation for determining the minimum number of theoretical stages in distillation column holds good, when the

Mixture (to be separated) shows negative deviation from ideality
Relative volatility is reasonably constant
Multicomponent distillation is involved
Mixture (to be separated) shows positive deviation from ideality

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