Mass Transfer
Azeotropic distillation is employed to separate

High boiling mixture
Mixture with very high relative volatility
Constant boiling mixture
Heat sensitive materials

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Mass Transfer
Plate towers are preferred to packed towers, when large temperature changes are involved, because of the reason that the

Pressure drop in the equipment will be very high
Packing may be crushed due to thermal expansion/contraction of the components of the equipments
Viscosity variation of the fluids may cause channeling/flooding
None of these

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