Mass Transfer
In steam distillation, the

Temperature is more than 100° C
Product must be immiscible with water
Temperature is 100°C
Temperature is higher than the boiling point of either component

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Mass Transfer
Solvent extraction is the terminology applied to the liquid-liquid extraction, which is preferred for the separation of the components of liquids, when

Viscosity of liquid components is very high
One of the liquid components is heat sensitive
One of the liquid components has very high affinity towards the solvent
Extracting solvent is cheaply & abundantly available

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