Chemical Engineering Thermodynamics
An irreversible process

Is the analog of linear frictionless motion in machines
Yields an amount of work less than that of a reversible process
Yields the maximum amount of work
Is an idealised visualisation of behaviour of a system

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Chemical Engineering Thermodynamics
Law of corresponding states says that

, two different gases behave similarly, if their reduced properties (i.e. P, V and T) are same
No gas can be liquified above the critical temperature, howsoever high the pressure may be
The molar heat of energy of gas at constant volume should be nearly constant (about 3 calories)
The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature

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