Chemical Engineering Thermodynamics
When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the

Arrehenius hypothesis
Law of corresponding state
Kopp's rule
Le-Chatelier principle

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Chemical Engineering Thermodynamics
The second law of thermodynamics states that

The total energy of system and surrounding remains the same
It is not possible to transfer heat from a lower temperature to a higher temperature
The energy change of a system undergoing any reversible process is zero
None of these

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