Chemical Engineering Thermodynamics
Claussius-Clayperon equation gives accurate result, when the

Volume in the liquid state is negligible compared with that in the vapour state
All of these
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
Vapour pressure is relatively low and the temperature does not vary over wide limits

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Chemical Engineering Thermodynamics
In the reaction, H₂ +I₂ ⇋ 2HI, addition of an inert gas will

Increase the total pressure and hence shift the equilibrium towards the right
Increase the partial pressure of I₂
Not effect the equilibrium conditions
Increase the partial pressure of H₂

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