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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DQ = CvdT + PdV
DQ = CpdT + Vdp
Tds = dE - PdV
DE = Tds - PdV

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Chemical Engineering Thermodynamics
In case of a close thermodynamic system, there is __________ across the boundaries.

No heat and mass transfer
None of these
No mass transfer but heat transfer
Mass and energy transfer

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Chemical Engineering Thermodynamics
Heat pump

Accomplishes only space heating in winter
Accomplishes only space cooling in summer
Accomplishes both A and B
Works on Carnot cycle

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Chemical Engineering Thermodynamics
The compressibility factor of a gas is given by (where, V₁ = actual volume of the gas V₂ = gas volume predicted by ideal gas law )

V₁/V₂
V₁.V₂
V₁-V₂
V₂/V₁

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Chemical Engineering Thermodynamics
For organic compounds, group contribution method can be used for the estimation of

Critical properties
Specific gravity
Specific volume
Thermal conductivity

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Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

A = H + TS
A = E - TS
None of these
A = H - TS

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