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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DQ = CpdT + Vdp
DE = Tds - PdV
DQ = CvdT + PdV

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Chemical Engineering Thermodynamics
Out of the following refrigration cycles, which one has the minimum COP (Co-efficient of performance)?

Vapour compression with a reversible expansion engine
Ordinary vapour compression cycle
Carnot cycle
Air cycle

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Chemical Engineering Thermodynamics
At normal boiling point, molar entropy of vaporisation is __________ Joule/K°.mole.

92
192
72
142

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Chemical Engineering Thermodynamics
A change in state involving a decrease in entropy can be spontaneous, only if

It takes place isothermally
It takes place at constant volume
It is exothermic
It is isenthalpic

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Chemical Engineering Thermodynamics
Specific __________ does not change during phase change at constant temperature and pressure.

Enthalpy
Gibbs energy
Entropy
Internal energy

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Chemical Engineering Thermodynamics
dW and dq are not the exact differential, because q and W are

Extensive properties
Intensive properties
State functions
Path functions

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