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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DQ = CvdT + PdV
DE = Tds - PdV
Tds = dE - PdV
DQ = CpdT + Vdp

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Chemical Engineering Thermodynamics
For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

Remains same
Decreases linearly
Increases
Decreases

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Chemical Engineering Thermodynamics
In which of the following reaction equilibria, the value of equilibrium constant Kp will be more than is Kc?

None of these
2HI ⇋ H₂ + I₂
2SO₂ + O₂ ⇋ 2SO₃
N₂O₄ ⇋ 2NO₂

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Chemical Engineering Thermodynamics
In vapour compression refrigeration system, if the evaporator temperature and the condenser temperatures are -13°C and 37°C respetively, the Carnot COP will be

Data insufficient, can't be found out
6.2
0.168
5.2

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Chemical Engineering Thermodynamics
1m³ of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be

154 K
35 K
174 K
274 K

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Chemical Engineering Thermodynamics
Degree of freedom of a system consisting of a gaseous mixture of H₂ and NH₃ will be

3
1
2
0

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