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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

Tds = dE - PdV
DQ = CvdT + PdV
DE = Tds - PdV
DQ = CpdT + Vdp

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Chemical Engineering Thermodynamics
Enthalpy changes over a constant pressure path are always zero for __________ gas.

An easily liquefiable
Any
A perfect
A real

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Chemical Engineering Thermodynamics
The melting point of paraffin wax (which contracts on solidification) __________ with pressure rise.

Decreases
Increases
Remains unchanged
Decreases linearly

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Chemical Engineering Thermodynamics
For an isothermal reversible compression of an ideal gas

DQ = dE
ΔE = ΔH = 0
Only ΔH =0
Only ΔE = 0

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Chemical Engineering Thermodynamics
The standard state of a gas (at a given temperature) is the state in which fugacity is equal to

Neither A nor B
Both A & B
Unity
Activity

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Chemical Engineering Thermodynamics
A gas has a volume of 27.3 c.c. at 0°C. Its volume at 10°C (if pressure remains unchanged) will be __________ c.c.

2.73
273
28.3
283

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