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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DE = Tds - PdV
DQ = CpdT + Vdp
Tds = dE - PdV
DQ = CvdT + PdV

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Chemical Engineering Thermodynamics
For a spontaneous process, free energy

Is zero
And entropy both decrease
Increases
Decreases whereas the entropy increases

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Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

A = H + TS
A = E - TS
None of these
A = H - TS

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Chemical Engineering Thermodynamics
The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the

Le-Chatelier's principle
Statement of Vant-Hoff equation
None of these
Lewis-Randall rule

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Chemical Engineering Thermodynamics
If different processes are used to bring about the same chemical reaction, the enthalpy change is same for all of them. This is __________ law.

Lavoisier and Laplace
Hess's
Kirchoff's
None of these

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Chemical Engineering Thermodynamics
In a working refrigerator, the value of COP is always

< 0
< 1
> 1

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