Mass Transfer
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of

Vapour pressure of component A to the partial pressure of A
Vapour pressure of component A to the total pressure
Vapour pressure of component A to that of component B
Partial pressure of component A to the total pressure

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Mass Transfer
To get high tray efficiency

Time of contact between the two phases should be less
Liquid entrainment should be severe
Interfacial surface between liquid and gas phase should be large
Gas velocity should be very low

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