Mass Transfer
When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of

Vapour pressure of component A to the total pressure
Vapour pressure of component A to the partial pressure of A
Vapour pressure of component A to that of component B
Partial pressure of component A to the total pressure

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Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Only liquid phase obeys Dalton's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only vapor phase follows Raoult's law

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