Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Same in both the phases
Replaced by chemical potential which is more in vapour phase
More in liquid phase
More in vapour phase

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Chemical Engineering Thermodynamics
A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is Φi yi P = Yi xi fi° where, Φ is a vapor fugacity component, Yi is the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of

Temperature and pressure only
Temperature, pressure and liquid composition xi only
Temperature, pressure, liquid composition xi and vapour composition yi
Temperature only

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