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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For organic compounds, group contribution method can be used for the estimation of

Specific gravity
Thermal conductivity
Specific volume
Critical properties

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Chemical Engineering Thermodynamics
At absolute zero temperature, all substances have the same

Entropy
Crystalline structure
Heat capacity
None of these

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Chemical Engineering Thermodynamics
The expression, ΔG = nRT .In P₂/P₁ , gives the free energy change

During heating of an ideal gas
During cooling of an ideal gas
Under reversible isothermal volume change
With pressure changes at constant temperature

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Chemical Engineering Thermodynamics
Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the

Heat of formation
Calorific value
Heat of reaction
Heat of combustion

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Chemical Engineering Thermodynamics
Joule-Thomson Co-efficient at any point on the inversion curve is

-ve
+ ve
∞

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂V)T = (∂P/∂T)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂P)T = -(∂V/∂T)P

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