Stoichiometry
The vapor pressures of benzene and toluene are 3 and 4/3 atmospheres respectively. A liquid feed of 0.4 moles of benzene and 0.6 moles of toluene is vapourised. Assuming that the products are in equilibrium, the vapor phase mole fraction of benzene is

0.6
0.8
0.4
0.2

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

Molal latent heat of vaporisation is constant within the limited temperature range
Volume in the liquid state is negligible compared with that in the vapor state
Vapor follows the ideal gas law
All of these

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