Stoichiometry
The vapor pressures of benzene and toluene are 3 and 4/3 atmospheres respectively. A liquid feed of 0.4 moles of benzene and 0.6 moles of toluene is vapourised. Assuming that the products are in equilibrium, the vapor phase mole fraction of benzene is

0.2
0.4
0.8
0.6

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

The component molecules are non polar and are of almost equal size
No component is concentrated at the surface of the solution
The attractive forces between like and unlike molecules are almost equal
In the formation of solution, chemical combination/molecular association between unlike molecules takes place

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