Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Of low probability of many body collisions
Of very large activation energy of many bodies
Many body collisions are not favoured energetically
Of requirement of very large concentration for such reactions

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Chemical Reaction Engineering
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Fast reaction in catalyst of large pore diameter
Slow reactions in catalyst of small pore diameter
Slow reactions in catalyst of large pore diameter
Fast reactions in catalyst of small pore diameter

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