Chemical Reaction Engineering
The heat of reaction

Depends on the pressure only
Is independent of the mechanism of reaction
Depends on the mechanism of reaction only
Depends on both pressure and mechanism of reaction

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Desorption of C
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase

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