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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its

All of these
Volume
Pressure
Temperature

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Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

None of these
A = H + TS
A = E - TS
A = H - TS

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Chemical Engineering Thermodynamics
With increase in pressure (above atmospheric pressure), the Cp of a gas

Increases
First decreases and then increases
Remains unchanged
Decreases

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Chemical Engineering Thermodynamics
The fusion of a crystalline solid at its melting point to form a liquid at the same temperature is accompanied by

Decrease of entropy
Decrease in enthalpy corresponding to evolution of heat
Increase in enthalpy corresponding to absorption of heat
No change in enthalpy

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Replaced by chemical potential which is more in vapour phase
More in liquid phase
More in vapour phase
Same in both the phases

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Chemical Engineering Thermodynamics
The absolute entropy for all crystalline substances at absolute zero temperature is

Indeterminate
Negative
More than zero
Zero

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