Stoichiometry
The equilibria relations in a multicom-ponent and multiphase system can not be calculated with the help of the

Theoretical equations
Experimental data
Emperical equations
Phase rule

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

Molal latent heat of vaporisation is constant within the limited temperature range
Vapor follows the ideal gas law
All of these
Volume in the liquid state is negligible compared with that in the vapor state

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