Stoichiometry
The net heat evolved or absorbed in a chemical process, i.e. total change in the enthalpy of the system is independent of the

Number of intermediate chemical reactions involved
State of aggregation & the state of combination at the beginning & the end of the reaction
None of these
Temperature & pressure

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

The attractive forces between like and unlike molecules are almost equal
The component molecules are non polar and are of almost equal size
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
No component is concentrated at the surface of the solution

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