Chemical Reaction Engineering
The effectiveness factor for large value of Thiele modulus (L√(K/D1)) of a solid catalysed first order reaction is equal to (where, L = length of the reactor, cm, D1 = diffusion co-efficient, cm²/second)

1/(L√(K/D1))
1
L√(K/D1)

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Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Of very large activation energy of many bodies
Many body collisions are not favoured energetically
Of requirement of very large concentration for such reactions
Of low probability of many body collisions

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