Chemical Reaction Engineering
Velocity of a reaction depends upon the

Temperature at which the reaction is carried
Nature of the reactants
Concentration of the reactants
All of these

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E
ΔHA + ΔHR
E + ΔHA - ΔHR
E + ΔHA

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Chemical Reaction Engineering
The heat of reaction

Is independent of the mechanism of reaction
Depends on both pressure and mechanism of reaction
Depends on the mechanism of reaction only
Depends on the pressure only

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