Mass Transfer
Steam distillation is not recommended to be used, if the

Material can not be distilled by indirect heating even under low pressure, because of the high boiling temperature
Liquids decompose, if distilled directly at atmospheric pressure
Azeotropic mixture is to be separated and the final product is miscible with water
Material to be distilled is thermally unstable or has the tendency to react with other components associated with it, at the boiling temperature

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Mass Transfer
When acetone is added in a two layer mixture of methyl isobutyl ketone and water at 30°C, the acetone distributes between the two layers and the composition of the layer follows two solubility curves. For this system,

Both the phases become identical at a particular common point on both the solubility curves called the plait point
The distribution curve which is a plot between x (acetone concentration in one phase) and y (acetone concentration in other phase) is analogous to x-y curve used in distillation and absorption termina
As the acetone concentration increases, the solubility curves approach each other
All of these

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