Spectroscopy
Vibrational spectroscopy is

a class of spectroscopic techniques which analyzes molecular motions
a large mass on a weak spring
a flashlight through a prism and shake it
an Infrared spectroscopy

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Spectroscopy
Why are rotational transitions of little use to a spectroscopist?

Because, in liquids and solids, spectral lines corresponding to rotational transitions are broadened as the result of molecular collisions and other interactions
All of these
Because rotational transitions are extremely rare
Because the energy required to induce a rotational transition is so small that it cannot be measured

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