If the pore diffusion controls in a catalytic reaction, the apparent activation energy Ea is equal to The intrinsic activation energy E ED/2 (E + ED) where ED is activation due to diffusion (E + ED)/2 TRUE ANSWER : ? YOUR ANSWER : ?
When all the limiting reactant is consumed in the reaction, the operational yield __________ the relative yield. Can be either greater or smaller than (depends on the type of reaction) Is greater than Equals Is smaller than TRUE ANSWER : ? YOUR ANSWER : ?
Oil is hydrogenated using nickel catalyst in a __________ reactor. Batch Slurry Fluidised bed Fixed bed TRUE ANSWER : ? YOUR ANSWER : ?
Transition state theory gives the rate constant as K α √T . e-E/RT K α eE/RT K α T . e-E/RT K α e-E/RT TRUE ANSWER : ? YOUR ANSWER : ?
The rate constant of a chemical reaction increases by 100 times when the temperature is increased from 400 °K to 500 °K. Assuming transition state theory is valid, the value of E/R is 8621°K 9210°K 8987°K 8764°K TRUE ANSWER : ? YOUR ANSWER : ?
A first order reaction requires two unequal sized CSTR. Which of the following gives higher yield ? Smaller reactor followed by larger one Data insufficient, can Either of the arrangement A or B will give the same yield Large reactor followed by smaller one TRUE ANSWER : ? YOUR ANSWER : ?
Fluidised bed reactor is characterised by Very small pressure drop Uniformity of temperature Comparatively smaller equipment Absence of continuous catalyst regeneration facility TRUE ANSWER : ? YOUR ANSWER : ?
If n = overall order of a chemical reaction. a = initial concentration of reactant. t = time required to complete a definite fraction of the reaction. Then pick out the correct relationship. T ∝ 1/an T ∝ 1/an - 1 T ∝ an T ∝ 1/an + 1 TRUE ANSWER : ? YOUR ANSWER : ?
What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? Litre/mole.second Moles/litre.second Litre/mole Litre/second TRUE ANSWER : ? YOUR ANSWER : ?
In the hydrodealkylation of toluene to benzene, the following reactions occur:C₇H₈ + H₂ → C₆H₆ + CH₄2C₆H₆ ⇋ C₁₂H₁₀ + H₂Toluene and hydrogen are fed to a reactor in a molar ratio 1:5.80% of the toluene gets converted and the selectivity of benzene(defined as moles of benzene formed/moles of toluene converted) is 90%. The fractional conversion of hydrogen is 0.144 0.16 0.136 0.152 TRUE ANSWER : ? YOUR ANSWER : ?