Mass Transfer
Pick out the wrong statement. Raoult's law does not apply, when the

Attractive forces between like and unlike molecules in the solution are approximately equal
Size of component molecules are not equal
Chemical combination or molecular association between unlike molecules takes place in the formation of solution
Component molecules are nonpolar

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Mass Transfer
McCabe-Thiele method

Uses weight fractions to express liquid and vapour composition
Can use any type of units
Uses molal units for material and energy balance
Is more accurate than Ponchan-Savarit method

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Mass Transfer
To get high tray efficiency

Gas velocity should be very low
Liquid entrainment should be severe
Time of contact between the two phases should be less
Interfacial surface between liquid and gas phase should be large

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