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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is

30554
4988.4
10373
4364.9

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Chemical Engineering Thermodynamics
If two pure liquid constituents are mixed in any proportion to give an ideal solution, there is no change in

Enthalpy
Both A & B
Volume
Neither A nor B

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Chemical Engineering Thermodynamics
Equilibrium constant decreases as the temperature

Decreases, for an exothermic reaction
Increases, for an exothermic reaction
Increases, for an endothermic reaction
None of these

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Chemical Engineering Thermodynamics
Cp of a gas at its critical temperature and pressure

Becomes zero
Equals 0.24 kcal/kmol °K
Equals 1 kcal/kmol °K
Becomes infinity

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Chemical Engineering Thermodynamics
The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

Contracts
Does not change in volume
Either A, B or C
Expands

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Chemical Engineering Thermodynamics
The expression, ΔG = nRT .In P₂/P₁ , gives the free energy change

During heating of an ideal gas
With pressure changes at constant temperature
During cooling of an ideal gas
Under reversible isothermal volume change

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