Stoichiometry
One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m³. It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m³. The amount of water vapour condensed (in kg) is

1
0.1
0.065

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Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water Xw in the vapour phase satisfies

0 < Xw < 0.5
Xw = 0.5
Xw = 1.0
0.5 < Xw < 1.0

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